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Ion Pairing and Solvent Relaxation Processes in Aqueous Solutions of Sodium Malonate and Sodium Succinate

Tromans, A. ; May, P.M. ; Hefter, Glenn ; Sato, T. ; Buchner, Richard



Abstract

Dielectric relaxation spectra have been measured for aqueous solutions of sodium malonate and sodium succinate over a wide range of frequencies ( 0.2 <= n/GHz <=89) and solute concentrations (0.025 <= c/M <= 1.0). In addition to the usual processes associated with bulk water, two further relaxation processes were detected. The faster of these, with a relaxation time of ~16 ps, is unusual and was ...

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