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Dielectric relaxation of aqueous electrolyte solutions. I. Solvent relaxation of 1:2, 2:1, and 2:2 electrolyte solutions

Barthel, Josef ; Hetzenauer, H. ; Buchner, Richard


Abstract

Complex permittivity measurements on aq. solns. of CdCl2, CuCl2, MgSO4, CdSO4, Na2SO4, Cd(ClO4)2, and MgCl2 in the frequency range from 0.9 to 90 GHz are reported. The data anal. reveals the superposition of 2 Debye dispersion steps for the solvent thus supporting multi-step relaxation mechanisms discussed for water in the literature. An addnl. low frequency process is found for CdCl2, CuCl2, ...

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