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Structure and Dynamics of 1-N-Alkyl-3-N-Methylimidazolium Tetrafluoroborate + Acetonitrile Mixtures

Stoppa, A. ; Hunger, J. ; Hefter, Glenn ; Buchner, Richard


A detailed investigation of the binary mixts. of the ionic liqs. (ILs) 1-N-R-3-N-methylimidazolium tetrafluoroborate (R = Et, Bu, n-hexyl) with the important mol. solvent acetonitrile (AN) over the entire compn. range has been made at 25 °C using broadband dielec. spectroscopy. All spectra showed two modes: a Cole-Cole (CC) mode centered at ∼2 GHz and a Debye mode centered at ∼50 GHz. However, ...


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