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A Liquid Inorganic Electrolyte Showing an Unusually High Lithium Ion Transference Number: A Concentrated Solution of LiAlCl4 in Sulfur Dioxide

Hartl, Robert, Fleischmann, Matthias, Gschwind, Ruth Maria, Winter, M. and Gores, H. J. (2013) A Liquid Inorganic Electrolyte Showing an Unusually High Lithium Ion Transference Number: A Concentrated Solution of LiAlCl4 in Sulfur Dioxide. Energies 6 (9), pp. 4448-4464.

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Date of publication of this fulltext: 12 Sep 2013 07:53

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Other URL: http://www.mdpi.com/1996-1073/6/9/4448


Abstract

We report on studies of an inorganic electrolyte: LiAlCl4 in liquid sulfur dioxide. Concentrated solutions show a very high conductivity when compared with typical electrolytes for lithium ion batteries that are based on organic solvents. Our investigations include conductivity measurements and measurements of transference numbers via nuclear magnetic resonance (NMR) and by a classical direct ...

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Item type:Article
Date:13 August 2013
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Heiner Jakob Gores
Identification Number:
ValueType
10.3390/en6094448DOI
Keywords:lithium ion transference number; lithium tetrachloroaluminate; sulfur dioxide; Hittorf’s method; diffusion-ordered spectroscopy (DOSY)-NMR
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:28833
Owner only: item control page

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