Zhang, Xin-Xing, Liang, Min, Hunger, Johannes, Buchner, Richard and Maroncelli, Mark (2013) Dielectric Relaxation and Solvation Dynamics in a Prototypical Ionic Liquid + Dipolar Protic Liquid Mixture: 1-Butyl-3-Methylimidazolium Tetrafluoroborate + Water. Journal of Physical Chemistry B 117, pp. 15356-15368.
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Abstract
Dielec. and solvation data on mixts. of 1-butyl-3-methylimidazolium tetrafluoroborate ([Im41][BF4]) + water are reported and used to examine the utility of dielec. solvation models. Dielec. permittivity and loss spectra (25 °C) were recorded over the frequency range 200 MHz to 89 GHz at 17 compns. and fit to a 4-Debye form. Dynamic Stokes shift measurements on the solute coumarin 153 (C153), ...
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2013 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identification Number: |
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| Keywords: | dielec relaxation solvation dynamics butylmethylimidazolium tetrafluoroborate ionic | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 29204 |
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