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Translational Diffusion in Mixtures of Imidazolium ILs with Polar Aprotic Molecular Solvents

Marekha, B. A. ; Kalugin, O. N. ; Bria, M. ; Buchner, Richard ; Idrissi, A.



Abstract

Self-​diffusion coeffs. of cations and solvent mols. were detd. with 1H NMR in mixts. of 1-​n-​butyl-​3-​methylimidazolium (Bmim+) tetrafluoroborate (BF4-​)​, hexafluorophosphate (PF6-​)​, trifluoromethanesulfonate (TfO-​)​, and bis(trifluoromethylsulfonyl)​imide (TFSI-​) with acetonitrile (AN)​, γ-​butyrolactone (γ-​BL)​, and propylene carbonate (PC) over the entire compn. range at 300 K. The ...

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