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A New Strategy for the Stereoselective Synthesis of 1,2,3-trisubstituted Cyclopropanes

Böhm, Claudius ; Schinnerl, Marina ; Bubert, Christian ; Zabel, Manfred ; Labahn, Thomas ; Parisini, Emilio ; Reiser, Oliver


The stereoselective synthesis of highly functionalized 1,2,3-trisubstituted cyclopropanes 1 and 2, starting from readily available furans 3 or N-protected pyrrole 4, is described. Furthermore, exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the title compounds.

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