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Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives

Kowalski, Konrad, Karpowicz, Rafal, Mlostoń, Grzegorz, Miesel, Dominique, Hildebrandt, Alexander, Lang, Heinrich, Czerwieniec, Rafal and Therrien, Bruno (2015) Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives. Dalton Transactions 44, pp. 6268-6276.

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Abstract

Three novel diferrocenyl complexes were prepared and characterised. 2,2-Diferrocenyl-4,5-dimethyl-3,6-dihydro-2H-thiopyran (1, sulphide) was accessible by the hetero-Diels–Alder reaction of diferrocenyl thioketone with 2,3-dimethyl-1,3-butadiene. Stepwise oxidation of 1 gave the respective oxides 2,2-diferrocenyl-4,5-dimethyl-3,6-dihydro-2H-thiopyran-1-oxide (2, sulfoxide) and ...

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Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identification Number:
ValueType
10.1039/C5DT00246JDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33297
Owner only: item control page

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