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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-338602
Abstract (German)
In dieser Arbeit wurden unterschiedliche chemische Systeme kleiner organischer Moleküle in Lösung, mittels moderner NMR-spektroskopischer Methoden, untersucht. In Kapitel zwei wird der lange kontrovers diskutierte Bildungsmechanismus des zentralen, organokatalytischen Enaminintermediates, während der Selbstaldolisierungsreaktion von Isopentanal, katalysiert durch Prolin aufgeklärt. Zu diesem ...

Translation of the abstract (English)
In this work, different systems of small organic molecules were investigated by means of modern solution NMR spectroscopy. In chapter two, the controversial discussed formation mechanism of the central organocatalytic enamine intermediate during the self-aldolization reaction of isopentanal, catalyzed by proline is elucidated by a combination of rate constant determination by NMR and theoretical ...
