Go to content
UR Home

NMR Spectroscopic Investigations on Small Organic Molecules: Catalyst Stabilities, Low-Abundance Conformers, Intermediates and Reaction Mechanisms

URN to cite this document:
urn:nbn:de:bvb:355-epub-338602
Haindl, Michael
Date of publication of this fulltext: 10 May 2017 11:14


Abstract (German)

In dieser Arbeit wurden unterschiedliche chemische Systeme kleiner organischer Moleküle in Lösung, mittels moderner NMR-spektroskopischer Methoden, untersucht. In Kapitel zwei wird der lange kontrovers diskutierte Bildungsmechanismus des zentralen, organokatalytischen Enaminintermediates, während der Selbstaldolisierungsreaktion von Isopentanal, katalysiert durch Prolin aufgeklärt. Zu diesem ...

plus

Translation of the abstract (English)

In this work, different systems of small organic molecules were investigated by means of modern solution NMR spectroscopy. In chapter two, the controversial discussed formation mechanism of the central organocatalytic enamine intermediate during the self-aldolization reaction of isopentanal, catalyzed by proline is elucidated by a combination of rate constant determination by NMR and theoretical ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons