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Decrypting Transition States by Light: Photoisomerization as a Mechanistic Tool in Brønsted Acid Catalysis

Renzi, P. , Hioe, J. and Gschwind, Ruth Maria (2017) Decrypting Transition States by Light: Photoisomerization as a Mechanistic Tool in Brønsted Acid Catalysis. Journal of the American Chemical Society 139 (19), pp. 6752-6760.

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Date of publication of this fulltext: 19 Jun 2017 13:33

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Other URL: http://dx.doi.org/10.1021/jacs.7b02539


Abstract

Despite the wide applicability of enantioselective Bronsted acid catalysis, experimental insight into transition states is Very rare, and most of the mechanistic knowledge is gained by theoretical calculations. Here, we present an alternative approach (decrypting transition state by light = DTS-hv), which enables the decryption of the transition states involved in chiral phosphoric acids ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1021/jacs.7b02539DOI
28472888PubMed ID
Keywords:TRANSFER HYDROGENATION; PHOSPHORIC-ACIDS; BOND ROTATION; IMINES; ACTIVATION; POWERFUL; ENANTIOSELECTIVITY; PHOTOREDUCTION; ISOMERIZATION; PHOSPHATES;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35754
Owner only: item control page

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