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Photoinitiated Carbonyl-Metathesis: Deoxygenative Reductive Olefination of Aromatic Aldehydes via Photoredox Catalysis

Wang, S., Nanjundappa, L., Hioe, J., Gschwind, R. M. and König, B. (2019) Photoinitiated Carbonyl-Metathesis: Deoxygenative Reductive Olefination of Aromatic Aldehydes via Photoredox Catalysis. Chemical Science 10, pp. 4580-4587.

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Date of publication of this fulltext: 21 Mar 2019 06:37

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Other URL: http://doi.org/10.1039/C9SC00711C


Abstract

Carbonyl-carbonyl olefination, known as McMurry reaction, represents a powerful strategy for the construction of olefins. However, catalytic variants that directly couple two carbonyl groups in a single reaction are less explored. Here, we report a photoredox-catalysis that uses B2Pin2 as terminal reductant and oxygen trap allowing for deoxygenative olefination of aromatic aldehydes under mild ...

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Item type:Article
Date:2019
Additional Information (public):Accepted Manuscript
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1039/C9SC00711CDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38446
Owner only: item control page

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