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Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough

Shafikov, Marsel Z. , Suleymanova, Alfiya F. , Czerwieniec, Rafał and Yersin, Hartmut (2017) Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough. Chemistry of Materials 29 (4), pp. 1708-1715.

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Other URL: http://doi.org/10.1021/acs.chemmater.6b05175


Abstract

A design strategy for the development of Ag(I)-based materials for thermally activated delayed fluorescence (TADF) is presented. Although Ag(I) complexes usually do not show TADF, the designed material, Ag(dbp)(P-2-nCB) [dbp = 2,9-di-n-butyl-1,10-phenanthroline, and P-2-nCB = nido-carborane-bis(diphenylphosphine)], shows a TADF efficiency breakthrough exhibiting an emission decay time of ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1021/acs.chemmater.6b05175DOI
Keywords:LIGHT-EMITTING-DIODES; CYCLOMETALATED IRIDIUM COMPLEXES; RESOLUTION OPTICAL SPECTROSCOPY; COPPER(I) HALIDE-COMPLEXES; LIGAND CHARGE-TRANSFER; PHOTOPHYSICAL PROPERTIES; ELECTROCHEMICAL-CELLS; SILVER(I) COMPLEXES; CU(I) COMPLEXES; EXCITED-STATES;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38684
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