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Photoluminescence of solid [Pt(II)(riboflavin)4]Cl2 at ambient conditions. Intraligand phosphorescence

Vogler, Arnd


Riboflavin reacts with Pt(C6H5CN)(2)Cl-2 in acetic add to yield insoluble [Pt(riboflavin)(4)]Cl-2. This brown compound shows a bright yellow-orange photoluminescence with lambda(max) = 635 nm. This emission is suggested to originate from the lowest-energy IL (riboflavin) triplet. This assignment is based on the comparison to the photoluminescence of solid riboflavin which exhibits a fluorescence ...


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