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NMR Spectroscopic Investigations of Brønsted Acid Catalyzed Transfer Hydrogenations

URN to cite this document:
urn:nbn:de:bvb:355-epub-407455
DOI to cite this document:
10.5283/epub.40745
Rothermel, Kerstin
Date of publication of this fulltext: 27 Jul 2020 06:00


Abstract (English)

In this thesis the interactions between different Brønsted acid catalysts and imines were investigated by NMR spectroscopy. First, the strong hydrogen bond between TRIP and various imines was investigated. In all cases the hydrogen geometry was not significantly affected by the substitution pattern of the imine. Therefore, the hydrogen bond seems to be a structural anchor of the pre-catalytic ...

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Translation of the abstract (German)

In dieser Arbeit wurden die Wechselwirkungen zwischen verschiedenen Brønsted Säure Katalysatoren und Iminen mittels NMR-Spektroskopie untersucht. Zunächst wurden die starken Wasserstoffbrücken zwischen TRIP und mehreren Iminen betrachtet. In allen Systemen wurde die Geometrie der Wasserstoffbrücke nur wenig von dem Substitutionsmuster der Imine beeinflusst. Somit scheint die Wasserstoffbrücke als ...

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