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Giant proximity exchange and valley splitting in TMDC/hBN/(Co, Ni) heterostructures
Zollner, Klaus
, Faria Junior, Paulo E. and Fabian, Jaroslav
(2020)
Giant proximity exchange and valley splitting in TMDC/hBN/(Co, Ni) heterostructures.
Physical Review B 101, 085112.
Date of publication of this fulltext: 24 Jan 2020 08:59
Article
DOI to cite this document: 10.5283/epub.41371
Abstract
We investigate the proximity-induced exchange coupling in transition-metal dichalcogenides (TMDCs), originating from spin injector geometries composed of hexagonal boron-nitride (hBN) and ferromagnetic (FM) cobalt (Co) or nickel (Ni), from first-principles. We employ a minimal tight-binding Hamiltonian that captures the low energy bands of the TMDCs around K and K' valleys, to extract orbital, ...
We investigate the proximity-induced exchange coupling in transition-metal dichalcogenides (TMDCs), originating from spin injector geometries composed of hexagonal boron-nitride (hBN) and ferromagnetic (FM) cobalt (Co) or nickel (Ni), from first-principles. We employ a minimal tight-binding Hamiltonian that captures the low energy bands of the TMDCs around K and K' valleys, to extract orbital, spin-orbit, and exchange parameters. The TMDC/hBN/FM heterostructure calculations show that due to the hBN buffer layer, the band structure of the TMDC is preserved, with an additional proximity-induced exchange splitting in the bands. We extract proximity exchange parameters in the 1-10 meV range, depending on the FM. The combination of proximity-induced exchange and intrinsic spin-orbit coupling (SOC) of the TMDCs, leads to a valley polarization, translating into magnetic exchange fields of tens of Tesla. The extracted parameters are useful for subsequent exciton calculations of TMDCs in the presence of a hBN/FM spin injector. Our calculated absorption spectra show a large splitting of the first exciton peak; in the case of MoS/hBN/Co we find a value of about 8 meV, corresponding to about 50 Tesla external magnetic field in bare TMDCs. The reason lies in the band structure, where a hybridization with Co
orbitals causes a giant valence band exchange splitting of more than 10 meV. Structures with Ni do not show any
level hybridization features, but still sizeable proximity exchange and exciton peak splittings of around 2 meV are present in the TMDCs.
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Details
| Item type | Article |
| Journal or Publication Title | Physical Review B |
| Volume: | 101 |
|---|---|
| Page Range: | 085112 |
| Date | February 2020 |
| Institutions | Physics > Institute of Theroretical Physics > Chair Professor Richter > Group Jaroslav Fabian |
| Dewey Decimal Classification | 500 Science > 530 Physics |
| Status | Published |
| Refereed | Yes, this version has been refereed |
| Created at the University of Regensburg | Yes |
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-413716 |
| Item ID | 41371 |
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