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A Phosphinine‐derived 1‐Phospha‐7‐bora‐norbornadiene: Frustrated Lewis Pair Type Activation of Triple Bonds

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Leitl, J. ; Jupp, A. R. ; Habraken, E. R. M. ; Streitferdt, V. ; Coburger, P. ; Scott, D. J. ; Gschwind, Ruth M. ; Müller, C. ; Slootweg, J. C. ; Wolf, Robert
License: Creative Commons: Attribution-Noncommercial 3.0
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Date of publication of this fulltext: 14 Feb 2020 12:37

This publication is part of the DEAL contract with Wiley.


Salt metathesis of 1-methyl-2,4,6-triphenylphosphacyclohexadienyl lithium and chlorobis(pentafluorophenyl)borane affords a 1-phospha-7-bora-norbornadiene derivative 2. The C equivalent to N triple bonds of nitriles insert into the P-B bond of 2 with concomitant C-B bond cleavage, whereas the C equivalent to C bonds of phenylacetylenes react with 2 to form lambda(4)-phosphabarrelenes. Even though ...


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