| Published Version Download ( PDF | 1MB) | License: Creative Commons Attribution Non-commercial No Derivatives 4.0 | |
Daten und pdf | Data Download ( ZIP Archive | 185MB) Repository staff only |
Perdeuterated Conjugated Polymers for Ultralow-Frequency Magnetic Resonance of OLEDs
Milster, Sebastian, Grünbaum, Tobias
, Bange, Sebastian
, Kurrmann, Simon, Kraus, Hermann, Stoltzfus, Dani M., Leung, Anna E., Darwish, Tamim A., Burn, Paul L., Boehme, Christoph and Lupton, John M.
(2020)
Perdeuterated Conjugated Polymers for Ultralow-Frequency Magnetic Resonance of OLEDs.
Angewandte Chemie International Edition 59 (24), pp. 9388-9392.
Date of publication of this fulltext: 09 Jun 2020 05:43
Article
DOI to cite this document: 10.5283/epub.43290
Abstract
The formation of excitons in OLEDs is spin dependent and can be controlled by electron-paramagnetic resonance, affecting device resistance and electroluminescence yield. We explore electrically detected magnetic resonance in the regime of very low magnetic fields (<1 mT). A pronounced feature emerges at zero field in addition to the conventional spin-1/2 Zeeman resonance for which the Larmor ...
The formation of excitons in OLEDs is spin dependent and can be controlled by electron-paramagnetic resonance, affecting device resistance and electroluminescence yield. We explore electrically detected magnetic resonance in the regime of very low magnetic fields (<1 mT). A pronounced feature emerges at zero field in addition to the conventional spin-1/2 Zeeman resonance for which the Larmor frequency matches that ofthe incident radiation. By comparing a conventional p-conjugated polymer as the active material to a perdeuterated analogue, we demonstrate the interplay between the zero-field feature and local hyperfine fields. The zero-field peak results from a quasistatic magnetic-field effect of the RF radiation for periods comparable to the carrier-pair lifetime. Zeeman resonances are resolved down to 3.2 MHz, approximately twice the Larmor frequency of an electron in Earth's field. However, since reducing hyperfine fields sharpens the Zeeman peak at the cost of an increased zero-field peak, we suggest that this result may constitute a fundamental low-field limit of magnetic resonance in carrier-pair-based systems. OLEDs offer an alternative solid-state platform to investigate the radical-pair mechanism of magnetic-field effects in photochemical reactions, allowing models of biological magnetoreception to be tested by measuring spin decoherence directly in the time domain by pulsed experiments.
Alternative links to fulltext
Involved Institutions
Details
| Item type | Article | ||||
| Journal or Publication Title | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley-VCH | ||||
|---|---|---|---|---|---|
| Open Access Type: | DEAL (Wiley) | ||||
| Volume: | 59 | ||||
| Number of Issue or Book Chapter: | 24 | ||||
| Page Range: | pp. 9388-9392 | ||||
| Date | 13 March 2020 | ||||
| Institutions | Physics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group John Lupton | ||||
| Identification Number |
| ||||
| Keywords | conjugated polymers, deuteration, isotopes, magnetic resonance, organic light-emitting diodes | ||||
| Dewey Decimal Classification | 500 Science > 530 Physics | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-432904 | ||||
| Item ID | 43290 |
Download Statistics
Download Statistics