Direkt zum Inhalt

Milster, Sebastian ; Grünbaum, Tobias ; Bange, Sebastian ; Kurrmann, Simon ; Kraus, Hermann ; Stoltzfus, Dani M. ; Leung, Anna E. ; Darwish, Tamim A. ; Burn, Paul L. ; Boehme, Christoph ; Lupton, John M.

Perdeuterated Conjugated Polymers for Ultralow-Frequency Magnetic Resonance of OLEDs

Milster, Sebastian, Grünbaum, Tobias , Bange, Sebastian , Kurrmann, Simon, Kraus, Hermann, Stoltzfus, Dani M., Leung, Anna E., Darwish, Tamim A., Burn, Paul L., Boehme, Christoph und Lupton, John M. (2020) Perdeuterated Conjugated Polymers for Ultralow-Frequency Magnetic Resonance of OLEDs. Angewandte Chemie International Edition 59 (24), S. 9388-9392.

Veröffentlichungsdatum dieses Volltextes: 09 Jun 2020 05:43
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.43290


Zusammenfassung

The formation of excitons in OLEDs is spin dependent and can be controlled by electron-paramagnetic resonance, affecting device resistance and electroluminescence yield. We explore electrically detected magnetic resonance in the regime of very low magnetic fields (<1 mT). A pronounced feature emerges at zero field in addition to the conventional spin-1/2 Zeeman resonance for which the Larmor ...

The formation of excitons in OLEDs is spin dependent and can be controlled by electron-paramagnetic resonance, affecting device resistance and electroluminescence yield. We explore electrically detected magnetic resonance in the regime of very low magnetic fields (<1 mT). A pronounced feature emerges at zero field in addition to the conventional spin-1/2 Zeeman resonance for which the Larmor frequency matches that ofthe incident radiation. By comparing a conventional p-conjugated polymer as the active material to a perdeuterated analogue, we demonstrate the interplay between the zero-field feature and local hyperfine fields. The zero-field peak results from a quasistatic magnetic-field effect of the RF radiation for periods comparable to the carrier-pair lifetime. Zeeman resonances are resolved down to 3.2 MHz, approximately twice the Larmor frequency of an electron in Earth's field. However, since reducing hyperfine fields sharpens the Zeeman peak at the cost of an increased zero-field peak, we suggest that this result may constitute a fundamental low-field limit of magnetic resonance in carrier-pair-based systems. OLEDs offer an alternative solid-state platform to investigate the radical-pair mechanism of magnetic-field effects in photochemical reactions, allowing models of biological magnetoreception to be tested by measuring spin decoherence directly in the time domain by pulsed experiments.



Beteiligte Einrichtungen


Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftAngewandte Chemie International Edition
Verlag:Wiley-VCH
Band:59
Nummer des Zeitschriftenheftes oder des Kapitels:24
Seitenbereich:S. 9388-9392
Datum13 März 2020
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Lupton > Arbeitsgruppe John Lupton
Identifikationsnummer
WertTyp
10.1002/anie.202002477DOI
Stichwörter / Keywordsconjugated polymers, deuteration, isotopes, magnetic resonance, organic light-emitting diodes
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-432904
Dokumenten-ID43290

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