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Easy Access to Enantiomerically Pure Heterocyclic Silicon-Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release

URN to cite this document:
urn:nbn:de:bvb:355-epub-444970
DOI to cite this document:
10.5283/epub.44497
Fontana, Nicolo ; Espinosa-Jalapa, Noel Angel ; Seidl, Michael ; Bauer, Jonathan O.
Date of publication of this fulltext: 21 Jan 2021 10:41

This publication is part of the DEAL contract with Wiley.


Abstract

Phosphonium ions are widely used in preparative organic synthesis and catalysis. The provision of new types of cations that contain both functional and chiral information is a major synthetic challenge and can open up new horizons in asymmetric cation-directed and Lewis acid catalysis. We discovered an efficient methodology towards new Si-chiral four-membered CPSSi* heterocyclic cations. Three ...

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