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Easy Access to Enantiomerically Pure Heterocyclic Silicon-Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release

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Fontana, Nicolo ; Espinosa-Jalapa, Noel Angel ; Seidl, Michael ; Bauer, Jonathan O.
Date of publication of this fulltext: 21 Jan 2021 10:41


Phosphonium ions are widely used in preparative organic synthesis and catalysis. The provision of new types of cations that contain both functional and chiral information is a major synthetic challenge and can open up new horizons in asymmetric cation‐directed and Lewis acid catalysis. We discovered an efficient methodology towards new Si‐chiral four‐membered CPSSi* heterocyclic cations. Three ...


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