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Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

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Arockiam, Percia-Beatrice ; Lennert, Ulrich ; Graf, Christina ; Rothfelder, Robin ; Scott, Daniel J. ; Fischer, Tillmann G. ; Zeitler, Kirsten ; Wolf, Robert
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 22 Jan 2021 07:24

This publication is part of the DEAL contract with Wiley.


Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. ...


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