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Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics
Toscano, Giuseppe
, Straubel, Jakob, Kwiatkowski, Alexander, Rockstuhl, Carsten, Evers, Ferdinand, Xu, Hongxing, Asger Mortensen, N.
and Wubs, Martijn
(2015)
Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics.
Nature Communications 6 (1), p. 7132.
Date of publication of this fulltext: 08 Jun 2021 06:18
Article
DOI to cite this document: 10.5283/epub.45952
Abstract
The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface ...
The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface effects in plasmonics necessarily requires a fully quantum-mechanical ab initio approach. We present a self-consistent hydrodynamic model (SC-HDM), where both the ground state and the excited state properties of an inhomogeneous electron gas can be determined. With this method we are able to explain the size-dependent surface resonance shifts of Na and Ag nanowires and nanospheres. The results we obtain are in good agreement with experiments and more advanced quantum methods. The SC-HDM gives accurate results with modest computational effort, and can be applied to arbitrary nanoplasmonic systems of much larger sizes than accessible with ab initio methods.
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| Item type | Article | ||||
| Journal or Publication Title | Nature Communications | ||||
| Publisher: | NATURE PUBLISHING GROUP | ||||
|---|---|---|---|---|---|
| Place of Publication: | LONDON | ||||
| Volume: | 6 | ||||
| Number of Issue or Book Chapter: | 1 | ||||
| Page Range: | p. 7132 | ||||
| Date | 27 May 2015 | ||||
| Additional Information (public) | beim Verlag kostenfrei zum Download! | ||||
| Institutions | Physics > Institute of Theroretical Physics > Chair Ferdinand Evers | ||||
| Identification Number |
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| Keywords | SURFACE-PLASMON DISPERSION; DENSITY-FUNCTIONAL THEORY; METAL-SURFACES; KINETIC-ENERGY; OPTICAL-RESPONSE; WORK FUNCTION; NONLOCAL RESPONSE; NANOWIRE DIMERS; ELECTRON-GAS; MODEL; | ||||
| Dewey Decimal Classification | 500 Science > 530 Physics | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Partially | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-459520 | ||||
| Item ID | 45952 |
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