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Toscano, Giuseppe ; Straubel, Jakob ; Kwiatkowski, Alexander ; Rockstuhl, Carsten ; Evers, Ferdinand ; Xu, Hongxing ; Asger Mortensen, N. ; Wubs, Martijn

Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics

Toscano, Giuseppe , Straubel, Jakob, Kwiatkowski, Alexander, Rockstuhl, Carsten, Evers, Ferdinand, Xu, Hongxing, Asger Mortensen, N. and Wubs, Martijn (2015) Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics. Nature Communications 6 (1), p. 7132.

Date of publication of this fulltext: 08 Jun 2021 06:18
Article
DOI to cite this document: 10.5283/epub.45952


Abstract

The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface ...

The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface effects in plasmonics necessarily requires a fully quantum-mechanical ab initio approach. We present a self-consistent hydrodynamic model (SC-HDM), where both the ground state and the excited state properties of an inhomogeneous electron gas can be determined. With this method we are able to explain the size-dependent surface resonance shifts of Na and Ag nanowires and nanospheres. The results we obtain are in good agreement with experiments and more advanced quantum methods. The SC-HDM gives accurate results with modest computational effort, and can be applied to arbitrary nanoplasmonic systems of much larger sizes than accessible with ab initio methods.



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleNature Communications
Publisher:NATURE PUBLISHING GROUP
Place of Publication:LONDON
Volume:6
Number of Issue or Book Chapter:1
Page Range:p. 7132
Date27 May 2015
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InstitutionsPhysics > Institute of Theroretical Physics > Chair Ferdinand Evers
Identification Number
ValueType
10.1038/ncomms8132DOI
KeywordsSURFACE-PLASMON DISPERSION; DENSITY-FUNCTIONAL THEORY; METAL-SURFACES; KINETIC-ENERGY; OPTICAL-RESPONSE; WORK FUNCTION; NONLOCAL RESPONSE; NANOWIRE DIMERS; ELECTRON-GAS; MODEL;
Dewey Decimal Classification500 Science > 530 Physics
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgPartially
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-459520
Item ID45952

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