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Toscano, Giuseppe ; Straubel, Jakob ; Kwiatkowski, Alexander ; Rockstuhl, Carsten ; Evers, Ferdinand ; Xu, Hongxing ; Asger Mortensen, N. ; Wubs, Martijn

Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics

Toscano, Giuseppe , Straubel, Jakob, Kwiatkowski, Alexander, Rockstuhl, Carsten, Evers, Ferdinand, Xu, Hongxing, Asger Mortensen, N. und Wubs, Martijn (2015) Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics. Nature Communications 6 (1), S. 7132.

Veröffentlichungsdatum dieses Volltextes: 08 Jun 2021 06:18
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.45952


Zusammenfassung

The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface ...

The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface effects in plasmonics necessarily requires a fully quantum-mechanical ab initio approach. We present a self-consistent hydrodynamic model (SC-HDM), where both the ground state and the excited state properties of an inhomogeneous electron gas can be determined. With this method we are able to explain the size-dependent surface resonance shifts of Na and Ag nanowires and nanospheres. The results we obtain are in good agreement with experiments and more advanced quantum methods. The SC-HDM gives accurate results with modest computational effort, and can be applied to arbitrary nanoplasmonic systems of much larger sizes than accessible with ab initio methods.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftNature Communications
Verlag:NATURE PUBLISHING GROUP
Ort der Veröffentlichung:LONDON
Band:6
Nummer des Zeitschriftenheftes oder des Kapitels:1
Seitenbereich:S. 7132
Datum27 Mai 2015
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InstitutionenPhysik > Institut für Theoretische Physik > Lehrstuhl Ferdinand Evers
Identifikationsnummer
WertTyp
10.1038/ncomms8132DOI
Stichwörter / KeywordsSURFACE-PLASMON DISPERSION; DENSITY-FUNCTIONAL THEORY; METAL-SURFACES; KINETIC-ENERGY; OPTICAL-RESPONSE; WORK FUNCTION; NONLOCAL RESPONSE; NANOWIRE DIMERS; ELECTRON-GAS; MODEL;
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenZum Teil
URN der UB Regensburgurn:nbn:de:bvb:355-epub-459520
Dokumenten-ID45952

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