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Influence of the Diphosphine Coordination Mode on the Structural and Optical Properties of Cyclometalated Platinum(II) Complexes: An Experimental and Theoretical Study on Intramolecular Pt···Pt and π···π Interactions

Barzegar-Kiadehi, S. Reza ; Golbon Haghighi, Mohsen ; Jamshidi, Mahboubeh ; Notash, Behrouz


The reaction of [Pt(C<^>N)(CF3CO2)(SMe2)] (1), in which CAN is either benzo[h]quinolinate (bhq), 1a, or 2-phenylpyridinate (ppy), 1b, with 1 equiv of bis(diphenylphosphino)methane (dppm) gave the bischelate complexes [Pt(C<^>N)dppm]CF3CO2 (2). The binuclear complexes [Pt-2(C<^>N)(2)(CF3CO2)(2)(mu-dppm)] (3) were prepared, using an unusual reaction pathway, by the addition of equimolar amount of ...


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