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Brønsted acid catalysis – the effect of 3,3′-substituents on the structural space and the stabilization of imine/phosphoric acid complexes

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Melikian, Maxime ; Gramüller, Johannes ; Hioe, Johnny ; Greindl, Julian ; Gschwind, Ruth M.
License: Creative Commons Attribution Non-commercial 4.0
PDF - Accepted Version
Date of publication of this fulltext: 03 Sep 2021 10:02


BINOL derived chiral phosphoric acids (CPAs) are widely known for their high selectivity. Numerous 3,3 0 substituents are used for a variety of stereoselective reactions and theoretical models of their effects are provided. However, experimental data about the structural space of CPA complexes in solution is extremely rare and so far restricted to NMR investigations of binary TRIP/imine complexes ...


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