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Noncovalent CH‐π and π‐π Interactions in Phosphoramidite Palladium(II) Complexes with Strong Conformational Preference

URN to cite this document:
urn:nbn:de:bvb:355-epub-493976
DOI to cite this document:
10.5283/epub.49397
Žabka, Matej ; Naviri, Lavakumar ; Gschwind, Ruth M.
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Date of publication of this fulltext: 14 Oct 2021 05:56

This publication is part of the DEAL contract with Wiley.


Abstract

The weak noncovalent interactions and flexibility of ligands play a key role in enantioselective metal-catalyzed reactions. In transition metal complexes and their catalytic applications, the experimental assessment and the design of key interactions is as difficult as the prediction of the enantioselectivities, especially for flexible, privileged ligands such as chiral phosphoramidites. ...

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