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Photophysical Activity and Host–Guest Behavior of Ruthenium Polypyridyl Catalysts Encapsulated in Cucurbit[10]uril

Luis, Ena T. ; Day, Anthony I. ; König, Burkhard ; Beves, Jonathon E.



Abstract

This work outlines a strategy to combine the use of visible light and confined spaces to form a supramolecular photocatalyst system. Polypyridyl ruthenium(II) complexes [Ru(bpy)(3)](2+) (bpy = 2,2'-bipyridine), [Ru(bpy)(2)(bpm)](2+) (bpm = 2,2'-bipyrimidine), and [Ru(bpy)(2)(bpz)](2+) (bpz = 2,2'-bipyrazine) are encapsulated in cucurbit[10]uril to form host-guest systems in aqueous solution. The ...

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