Ternary complexes of chiral disulfonimides in transfer-hydrogenation of imines: the relevance of late intermediates in ion pair catalysis

URN to cite this document:: urn:nbn:de:bvb:355-epub-511373
DOI to cite this document:: 10.5283/epub.51137

Žabka, M. ; Gschwind, R. M.

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Date of publication of this fulltext: 07 Dec 2021 07:00

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Abstract

In ion pairing catalysis, the structures of late intermediates and transition states are key to understanding and further development of the field. Typically, a plethora of transition states is explored computationally. However, especially for ion pairs the access to energetics via computational chemistry is difficult and experimental data is rare. Here, we present for the first time extensive ...