Intermolecular Photocatalytic Chemo‐, Stereo‐ and Regioselective Thiol–Yne–Ene Coupling Reaction

URN to cite this document:: urn:nbn:de:bvb:355-epub-518577
DOI to cite this document:: 10.5283/epub.51857

Burykina, Julia V.

; Kobelev, Andrey D.

; Shlapakov, Nikita S.

; Kostyukovich, Alexander Yu. ; Fakhrutdinov, Artem N. ; König, Burkhard

; Ananikov, Valentine P.

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Date of publication of this fulltext: 07 Mar 2022 08:01

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Abstract

The first example of an intermolecular thiol-yne-ene coupling reaction is reported for the one-pot construction of C-S and C-C bonds. Thiol-yne-ene coupling opens a new dimension in building molecular complexity to access densely functionalized products. The employment of Eosin Y/DBU/MeOH photocatalytic system suppresses hydrogen atom transfer (HAT) and associative reductant upconversion (via C-S ...