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Intermolecular Photocatalytic Chemo‐, Stereo‐ and Regioselective Thiol–Yne–Ene Coupling Reaction

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Burykina, Julia V. ; Kobelev, Andrey D. ; Shlapakov, Nikita S. ; Kostyukovich, Alexander Yu. ; Fakhrutdinov, Artem N. ; König, Burkhard ; Ananikov, Valentine P.
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Date of publication of this fulltext: 07 Mar 2022 08:01

This publication is part of the DEAL contract with Wiley.


The first example of an intermolecular thiol-yne-ene coupling reaction is reported for the one-pot construction of C-S and C-C bonds. Thiol-yne-ene coupling opens a new dimension in building molecular complexity to access densely functionalized products. The employment of Eosin Y/DBU/MeOH photocatalytic system suppresses hydrogen atom transfer (HAT) and associative reductant upconversion (via C-S ...


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