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Ultrafast transient absorption and solvation of a super-photoacid in acetoneous environments

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Knorr, Johannes ; Sülzner, Niklas ; Geissler, Bastian ; Spies, Christian ; Grandjean, Alexander ; Kutta, Roger Jan ; Jung, Gregor ; Nuernberger, Patrick
[img]License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 05 Oct 2022 04:50

This publication is part of the DEAL contract with Springer.


The phenomenon of photoacidity, i.e., an increase in acidity by several orders of magnitude upon electronic excitation, is frequently encountered in aromatic alcohols capable of transferring a proton to a suitable acceptor. A promising new class of neutral super-photoacids based on pyranine derivatives has been shown to exhibit pronounced solvatochromic effects. To disclose the underlying ...


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