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Highly Chemoselective Catalytic Photooxidations by Using Solvent as a Sacrificial Electron Acceptor

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Obertik, Robert ; Chudoba, Josef ; Šturala, Jiri ; Tarábek, Ján ; Ludvíková, Lucie ; Slanina, Tomas ; König, Burkhard ; Cibulka, Radek
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Date of publication of this fulltext: 17 Oct 2022 08:42


Catalyst recovery is an integral part of photoredox catalysis. It is often solved by adding another component-a sacrificial agent-whose role is to convert the catalyst back into its original oxidation state. However, an additive may cause a side reaction thus decreasing the selectivity and overall efficiency. Herein, we present a novel approach towards chemoselective photooxidation reactions ...


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