Superchaotropic Polyoxometalates – From Fundamental Investigations Towards Potential Applications - University of Regensburg Publication Server

Item type:	Thesis of the University of Regensburg (PhD)
Open Access Type:	Primary Publication
Date:	1 October 2024
Referee:	Prof. Dr. Arno Pfitzner and Dr. habil Pierre Bauduin and Prof. Dr. Werner Kunz
Date of exam:	24 October 2022
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Keywords:	Superchaotropicity, Polyoxometalates, Ion Effects
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	53125

Abstract (English)

In 2015, the remarkable propensity of low charge density nanometric anions, such as polyoxometalates (POMs), to associate non-covalently with non-ionic surfaces and (oligomeric) solutes, was demonstrated – a phenomenon called superchaotropicity. Within this thesis different aspects of superchaotropicity are investigated ranging from fundamental investigations on the driving force and the ...

Abstract (English)

In 2015, the remarkable propensity of low charge density nanometric anions, such as polyoxometalates (POMs), to associate non-covalently with non-ionic surfaces and (oligomeric) solutes, was demonstrated – a phenomenon called superchaotropicity. Within this thesis different aspects of superchaotropicity are investigated ranging from fundamental investigations on the driving force and the implications of the superchaotropic effect to potential applications, such as in solubilization processes or in photocatalysis.

Translation of the abstract (German)

2015 wurde die bemerkenswerte Eigenschaft von nanometrischen Ionen mit niedriger Ladungsdichte, wie zum Beispiel Polyoxometallaten (POMs), berichtet, an nicht-ionische Grenzflächen und (oligomere) Moleküle nicht-kovalent zu binden – ein Phänomen, das Superchaotropie bezeichnet wird. In dieser Dissertation werden unterschiedliche Aspekte hinsichtlich der fundamentalen physikochemischen Triebkraft ...

Translation of the abstract (German)

2015 wurde die bemerkenswerte Eigenschaft von nanometrischen Ionen mit niedriger Ladungsdichte, wie zum Beispiel Polyoxometallaten (POMs), berichtet, an nicht-ionische Grenzflächen und (oligomere) Moleküle nicht-kovalent zu binden – ein Phänomen, das Superchaotropie bezeichnet wird. In dieser Dissertation werden unterschiedliche Aspekte hinsichtlich der fundamentalen physikochemischen Triebkraft der Superchaotropie bis hin zu potentiellen Anwendungen derer in beispielsweise Lösungsprozessen oder der Photokatalyse beleuchtet.

Superchaotropic Polyoxometalates – From Fundamental Investigations Towards Potential Applications

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Abstract (English)

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Translation of the abstract (German)

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