Hydrogen‐Bond‐Modulated Nucleofugality of SeIII Species to Enable Photoredox‐Catalytic Semipinacol Manifolds

URN to cite this document:: urn:nbn:de:bvb:355-epub-531875
DOI to cite this document:: 10.5283/epub.53187

Park, Sooyoung ; Dutta, Amit K. ; Allacher, Carina ; Abramov, Alex

; Dullinger, Philipp ; Kuzmanoska, Katerina ; Fritsch, Daniela ; Hitzfeld, Patrick

; Horinek, Dominik

; Rehbein, Julia ; Nuernberger, Patrick

; Gschwind, Ruth Maria

; Breder, Alexander

License: Creative Commons Attribution Non-commercial Share Alike 4.0
PDF - Published Version
(7MB)

Date of publication of this fulltext: 14 Nov 2022 09:15

Alternative links to fulltext:DOI Publisher

Details

Preview

Export bibliographical data

Abstract

Chemical bond activations mediated by H-bond interactions involving highly electronegative elements such as nitrogen and oxygen are powerful tactics in modern catalysis research. On the contrary, kindred catalytic regimes in which heavier, less electronegative elements such as selenium engage in H-bond interactions to co-activate C−Se σ-bonds under oxidative conditions are elusive. Traditional ...