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Hydrogen‐Bond‐Modulated Nucleofugality of SeIII Species to Enable Photoredox‐Catalytic Semipinacol Manifolds

URN to cite this document:
urn:nbn:de:bvb:355-epub-531875
DOI to cite this document:
10.5283/epub.53187
Park, Sooyoung ; Dutta, Amit K. ; Allacher, Carina ; Abramov, Alex ; Dullinger, Philipp ; Kuzmanoska, Katerina ; Fritsch, Daniela ; Hitzfeld, Patrick ; Horinek, Dominik ; Rehbein, Julia ; Nuernberger, Patrick ; Gschwind, Ruth Maria ; Breder, Alexander
Date of publication of this fulltext: 14 Nov 2022 09:15

This publication is part of the DEAL contract with Wiley.


Abstract

Chemical bond activations mediated by H-bond interactions involving highly electronegative elements such as nitrogen and oxygen are powerful tactics in modern catalysis research. On the contrary, kindred catalytic regimes in which heavier, less electronegative elements such as selenium engage in H-bond interactions to co-activate C-Se sigma-bonds under oxidative conditions are elusive. ...

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