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Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)–H fluorinations

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Yakubov, Shahboz ; Stockerl, W. J. ; Tian, Xianhai ; Shahin, A. ; Mandigma, M. J. P. ; Gschwind, Ruth Maria ; Barham, Joshua P.
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Date of publication of this fulltext: 18 Nov 2022 14:37


Of the methods for direct fluorination of unactivated C(sp3)–H bonds, photosensitization of SelectFluor is a promising approach. Although many substrates can be activated with photosensitizing catalysts, issues remain that hamper fluorination of complex molecules. Alcohol- or amine-containing functional groups are not tolerated, fluorination regioselectivity follows factors endogenous to the ...


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