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First-principles insights into the spin-valley physics of strained transition metal dichalcogenides monolayers
Faria Junior, Paulo Eduardo, Zollner, Klaus, Woźniak, Tomasz
, Kurpas, Marcin, Gmitra, Martin
und Fabian, Jaroslav
(2022)
First-principles insights into the spin-valley physics of strained transition metal dichalcogenides monolayers.
New Journal of Physics 24 (8), 083004.
Veröffentlichungsdatum dieses Volltextes: 06 Dez 2022 13:59
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.53310
Zusammenfassung
Transition metal dichalcogenides (TMDCs) are ideal candidates to explore the manifestation of spin-valley physics under external stimuli. In this study, we investigate the influence of strain on the spin and orbital angular momenta, effective g-factors, and Berry curvatures of several monolayer TMDCs (Mo and W based) using a full ab initio approach. At the K-valleys, we find a surprising decrease ...
Transition metal dichalcogenides (TMDCs) are ideal candidates to explore the manifestation of spin-valley physics under external stimuli. In this study, we investigate the influence of strain on the spin and orbital angular momenta, effective g-factors, and Berry curvatures of several monolayer TMDCs (Mo and W based) using a full ab initio approach. At the K-valleys, we find a surprising decrease of the conduction band spin expectation value for compressive strain, consequently increasing the dipole strength of the dark exciton by more than one order of magnitude (for similar to 1%-2% <i strain variation). We also predict the behavior of direct excitons g-factors under strain: tensile (compressive) strain increases (decreases) the absolute value of g-factors. Strain variations of similar to 1% modify the bright (A and B) excitons g-factors by similar to 0.3 (0.2) for W (Mo) based compounds and the dark exciton g-factors by similar to 0.5 (0.3) for W (Mo) compounds. Our predictions could be directly visualized in magneto-optical experiments in strained samples at low temperature. Additionally, our calculations strongly suggest that strain effects are one of the possible causes of g-factor fluctuations observed experimentally. By comparing the different TMDC compounds, we reveal the role of spin-orbit coupling (SOC): the stronger the SOC, the more sensitive are the spin-valley features under applied strain. Consequently, monolayer WSe2 is a formidable candidate to explore the role of strain on the spin-valley physics. We complete our analysis by considering the side valleys, Gamma and Q points, and by investigating the influence of strain in the Berry curvature. In the broader context of valley- and strain-tronics, our study provides fundamental microscopic insights into the role of strain in the spin-valley physics of TMDCs, which are relevant to interpret experimental data in monolayer TMDCs as well as TMDC-based van der Waals heterostructures.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | New Journal of Physics | ||||
| Verlag: | IOP PUBLISHING LTD | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | BRISTOL | ||||
| Band: | 24 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 8 | ||||
| Seitenbereich: | 083004 | ||||
| Datum | 9 August 2022 | ||||
| Institutionen | Physik > Institut für Theoretische Physik > Lehrstuhl Professor Richter > Arbeitsgruppe Jaroslav Fabian | ||||
| Identifikationsnummer |
| ||||
| Stichwörter / Keywords | EMERGING PHOTOLUMINESCENCE; BLOCH ELECTRONS; BERRY PHASE; WSE2; SEMICONDUCTORS; POLARIZATION; EXCITATIONS; EXCITONS; GRAPHENE; MOS2; spin-valley; valley Zeeman; spin-mixing; TMDC; valleytronics; straintronics; strain | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 530 Physik | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-533109 | ||||
| Dokumenten-ID | 53310 |
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