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Faria Junior, Paulo Eduardo ; Zollner, Klaus ; Woźniak, Tomasz ; Kurpas, Marcin ; Gmitra, Martin ; Fabian, Jaroslav

First-principles insights into the spin-valley physics of strained transition metal dichalcogenides monolayers

Faria Junior, Paulo Eduardo, Zollner, Klaus, Woźniak, Tomasz , Kurpas, Marcin, Gmitra, Martin und Fabian, Jaroslav (2022) First-principles insights into the spin-valley physics of strained transition metal dichalcogenides monolayers. New Journal of Physics 24 (8), 083004.

Veröffentlichungsdatum dieses Volltextes: 06 Dez 2022 13:59
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.53310


Zusammenfassung

Transition metal dichalcogenides (TMDCs) are ideal candidates to explore the manifestation of spin-valley physics under external stimuli. In this study, we investigate the influence of strain on the spin and orbital angular momenta, effective g-factors, and Berry curvatures of several monolayer TMDCs (Mo and W based) using a full ab initio approach. At the K-valleys, we find a surprising decrease ...

Transition metal dichalcogenides (TMDCs) are ideal candidates to explore the manifestation of spin-valley physics under external stimuli. In this study, we investigate the influence of strain on the spin and orbital angular momenta, effective g-factors, and Berry curvatures of several monolayer TMDCs (Mo and W based) using a full ab initio approach. At the K-valleys, we find a surprising decrease of the conduction band spin expectation value for compressive strain, consequently increasing the dipole strength of the dark exciton by more than one order of magnitude (for similar to 1%-2% <i strain variation). We also predict the behavior of direct excitons g-factors under strain: tensile (compressive) strain increases (decreases) the absolute value of g-factors. Strain variations of similar to 1% modify the bright (A and B) excitons g-factors by similar to 0.3 (0.2) for W (Mo) based compounds and the dark exciton g-factors by similar to 0.5 (0.3) for W (Mo) compounds. Our predictions could be directly visualized in magneto-optical experiments in strained samples at low temperature. Additionally, our calculations strongly suggest that strain effects are one of the possible causes of g-factor fluctuations observed experimentally. By comparing the different TMDC compounds, we reveal the role of spin-orbit coupling (SOC): the stronger the SOC, the more sensitive are the spin-valley features under applied strain. Consequently, monolayer WSe2 is a formidable candidate to explore the role of strain on the spin-valley physics. We complete our analysis by considering the side valleys, Gamma and Q points, and by investigating the influence of strain in the Berry curvature. In the broader context of valley- and strain-tronics, our study provides fundamental microscopic insights into the role of strain in the spin-valley physics of TMDCs, which are relevant to interpret experimental data in monolayer TMDCs as well as TMDC-based van der Waals heterostructures.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftNew Journal of Physics
Verlag:IOP PUBLISHING LTD
Ort der Veröffentlichung:BRISTOL
Band:24
Nummer des Zeitschriftenheftes oder des Kapitels:8
Seitenbereich:083004
Datum9 August 2022
InstitutionenPhysik > Institut für Theoretische Physik > Lehrstuhl Professor Richter > Arbeitsgruppe Jaroslav Fabian
Identifikationsnummer
WertTyp
10.1088/1367-2630/ac7e21DOI
Stichwörter / KeywordsEMERGING PHOTOLUMINESCENCE; BLOCH ELECTRONS; BERRY PHASE; WSE2; SEMICONDUCTORS; POLARIZATION; EXCITATIONS; EXCITONS; GRAPHENE; MOS2; spin-valley; valley Zeeman; spin-mixing; TMDC; valleytronics; straintronics; strain
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-533109
Dokumenten-ID53310

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