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Access to Enantiomerically Pure P ‐Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions

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Huber, Tanja ; Espinosa‐Jalapa, Noel Angel ; Bauer, Jonathan O.
Date of publication of this fulltext: 10 Jan 2023 08:01

This publication is part of the DEAL contract with Wiley.


Stereochemically pure phosphines with phosphorus-heteroatom bonds and P-centered chirality are a promising class of functional building blocks for the design of chiral ligands and organocatalysts. A route to enantiomerically pure primary aminophosphine sulfides was opened through stereospecific reductive C-N bond cleavage of phosphorus(V) precursors by lithium in liquid ammonia. The ...


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