Access to Enantiomerically Pure P ‐Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions

URN to cite this document:: urn:nbn:de:bvb:355-epub-535006
DOI to cite this document:: 10.5283/epub.53500

Huber, Tanja

; Espinosa‐Jalapa, Noel Angel ; Bauer, Jonathan O.

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 10 Jan 2023 08:01

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Abstract

Stereochemically pure phosphines with phosphorus-heteroatom bonds and P-centered chirality are a promising class of functional building blocks for the design of chiral ligands and organocatalysts. A route to enantiomerically pure primary aminophosphine sulfides was opened through stereospecific reductive C-N bond cleavage of phosphorus(V) precursors by lithium in liquid ammonia. The ...