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Synthesis of 1,3‐Dioxan‐2‐ones by Photo‐Aerobic Selenium‐π‐Acid Multicatalysis

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Müller, Kilian A. ; Nagel, Carolin H. ; Breder, Alexander
Date of publication of this fulltext: 17 Jan 2023 08:34

This publication is part of the DEAL contract with Wiley.


An expedient method for the synthesis of cyclic carbonates from homoallylic carbonic acid esters by means of photo-aerobic selenium-π-acid multicatalysis is reported. Until now, conceptually related methods commonly relied either on the stoichiometric addition of electrophiles onto the substrate's alkene moiety or the presence of pre-installed leaving groups in allylic position of said alkene to ...


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