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Synthesis of 1,3‐Dioxan‐2‐ones by Photo‐Aerobic Selenium‐π‐Acid Multicatalysis

URN to cite this document:
urn:nbn:de:bvb:355-epub-535394
DOI to cite this document:
10.5283/epub.53539
Müller, Kilian A. ; Nagel, Carolin H. ; Breder, Alexander
Date of publication of this fulltext: 17 Jan 2023 08:34

This publication is part of the DEAL contract with Wiley.


Abstract

An expedient method for the synthesis of cyclic carbonates from homoallylic carbonic acid esters by means of photo-aerobic selenium-π-acid multicatalysis is reported. Until now, conceptually related methods commonly relied either on the stoichiometric addition of electrophiles onto the substrate's alkene moiety or the presence of pre-installed leaving groups in allylic position of said alkene to ...

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