Synthesis of 1,3‐Dioxan‐2‐ones by Photo‐Aerobic Selenium‐π‐Acid Multicatalysis

URN to cite this document:: urn:nbn:de:bvb:355-epub-535394
DOI to cite this document:: 10.5283/epub.53539

Müller, Kilian A. ; Nagel, Carolin H. ; Breder, Alexander

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF
(1MB)

Date of publication of this fulltext: 17 Jan 2023 08:34

Alternative links to fulltext:DOI Publisher

Details

Preview

Export bibliographical data

Abstract

An expedient method for the synthesis of cyclic carbonates from homoallylic carbonic acid esters by means of photo-aerobic selenium-π-acid multicatalysis is reported. Until now, conceptually related methods commonly relied either on the stoichiometric addition of electrophiles onto the substrate's alkene moiety or the presence of pre-installed leaving groups in allylic position of said alkene to ...