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Stereochemically Pure Si‐Chiral Aminochlorosilanes

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Kümper, Manuel ; Götz, Tobias ; Espinosa‐Jalapa, Noel Angel ; Falk, Alexander ; Rothfelder, Robin ; Bauer, Jonathan O.
Date of publication of this fulltext: 25 Jul 2023 07:55

This publication is part of the DEAL contract with Wiley.


Silicon-based compounds with stereochemical information and convertible functional units are valuable building blocks in synthetic chemistry. Si-stereogenic aminochlorosilanes are built up by Si−N bond formation between an achiral dichlorosilane and a chiral enantiomerically pure primary amine. Both diastereomers could be isolated as stereochemically pure single-crystals by fractional ...


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