Regioselective Rhodium‐Catalyzed 1,2‐Hydroboration of Pyridines and Quinolines Enabled by the Tris(8‐quinolinyl)phosphite Ligand**

URN to cite this document:: urn:nbn:de:bvb:355-epub-546229
DOI to cite this document:: 10.5283/epub.54622

Chacón‐Terán, Miguel A. ; Landaeta, Vanessa R.

; Wolf, Robert

; Rodríguez‐Lugo, Rafael E.

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 29 Aug 2023 04:14

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Abstract

A Rh(I) complex [κ2(P,N)-{P(Oquin)3}RhCl(PPh3)] (1) bearing the P,N ligand tris(8-quinolinyl)phosphite, P(Oquin)3, has been synthesized and structurally characterized. The molecular structure of complex 1 shows that P(Oquin)3 acts as a bidentate P,N chelate ligand. Reactivity studies of 1 reveal that the triphenylphosphine ligand can be replaced by Pcy3 or removed upon oxidation with concomitant ...