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Regioselective Rhodium‐Catalyzed 1,2‐Hydroboration of Pyridines and Quinolines Enabled by the Tris(8‐quinolinyl)phosphite Ligand**

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Chacón‐Terán, Miguel A. ; Landaeta, Vanessa R. ; Wolf, Robert ; Rodríguez‐Lugo, Rafael E.
Date of publication of this fulltext: 29 Aug 2023 04:14

This publication is part of the DEAL contract with Wiley.


A Rh(I) complex [κ2(P,N)-{P(Oquin)3}RhCl(PPh3)] (1) bearing the P,N ligand tris(8-quinolinyl)phosphite, P(Oquin)3, has been synthesized and structurally characterized. The molecular structure of complex 1 shows that P(Oquin)3 acts as a bidentate P,N chelate ligand. Reactivity studies of 1 reveal that the triphenylphosphine ligand can be replaced by Pcy3 or removed upon oxidation with concomitant ...


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