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Excited states of methano-bridged [10]-, [14]-, and [18]annulenes. Evidence for strong transannular interaction, and relation to homoaromaticity

Dewey, Harry J., Deger, Hans, Froelich, Wolfgang, Dick, Bernhard, Klingensmith, Kenneth A., Hohlneicher, Georg, Vogel, Emanuel and Michl, Josef (1980) Excited states of methano-bridged [10]-, [14]-, and [18]annulenes. Evidence for strong transannular interaction, and relation to homoaromaticity. Journal of the American Chemical Society 102 (21), pp. 6412-6417.

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Measurements of the absorption, polarized fluorescence, and MCD of 1,6-methano[10]annulene, 1,6:8,13-bismethano[14]annulene, and 1,6:8,17:10,15-trismethano[18]annulene along with the semiempirical p-electron and AVE calcns. on these and related annulenes are reported. The transannular interaction in the methano-bridged annulenes is strong, and these homoarom. mols. can be viewed as examples of ...


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Item type:Article
Additional Information (public):CAN 93:203809 22-8 Physical Organic Chemistry 2443-46-1; 14458-51-6; 68568-08-1 Role: PRP (Properties) (transannular interaction in)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
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Keywords:Annulenes, Role: PRP (Properties) (methano-bridged, transannular interaction in); Magnetic circular dichroism; Oscillator strength; Ultraviolet and visible spectra (of methano-bridged annulenes); Molecular orbital (CNDO/S, of methano-bridged annulenes); Energy level excitation (electronic, of methano-bridged annulenes); Aromaticity (homo-, of methanoannulenes); Fluorescence (polarized, of methano-bridged annulenes); transannular interaction methanoannulene MO; fluorescence methanoannulene; UV methanoannulene; homoaromaticity methanoannulene MO; electronic transition methanoannulene MO; magnetic CD methanoannulene
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Item ID:5494
Owner only: item control page


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