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Rothe, Manuel ; Müller, Eva ; Denk, Patrick ; Kunz, Werner

Ionic Liquids Based on the Concept of Melting Point Lowering Due to Ethoxylation

Rothe, Manuel , Müller, Eva, Denk, Patrick und Kunz, Werner (2021) Ionic Liquids Based on the Concept of Melting Point Lowering Due to Ethoxylation. Molecules 26 (13), S. 4034.

Veröffentlichungsdatum dieses Volltextes: 19 Dez 2023 06:37
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.55199


Zusammenfassung

Most of the commonly used Ionic Liquids (ILs) contain bulky organic cations with suitable anions. With our COMPLET (Concept of Melting Point Lowering due to Ethoxylation), we follow a different approach. We use simple, low-toxic, cheap, and commercially available anions of the type C-x(EO)(y)CH2COO- to liquefy presumably any simple metal ion, independently of its charge. In the simplest case, the ...

Most of the commonly used Ionic Liquids (ILs) contain bulky organic cations with suitable anions. With our COMPLET (Concept of Melting Point Lowering due to Ethoxylation), we follow a different approach. We use simple, low-toxic, cheap, and commercially available anions of the type C-x(EO)(y)CH2COO- to liquefy presumably any simple metal ion, independently of its charge. In the simplest case, the cation can be sodium or lithium, but synthesis of Ionic Liquids is also possible with cations of higher valences such as transition or rare earth metals. Anions with longer alkyl chains are surface active and form surface active ionic liquids (SAILs), which combine properties of ionic and nonionic surfactants at room temperature. They show significant structuring even in their pure state, i.e., in the absence of water or any other added solvent. This approach offers new application domains that go far beyond the common real or hypothetical use of classical Ionic Liquids. Possible applications include the separation of rare earth metals, the use as interesting media for metal catalysis, or the synthesis of completely new materials (for example, in analogy to metal organic frameworks).



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftMolecules
Verlag:MDPI
Ort der Veröffentlichung:BASEL
Band:26
Nummer des Zeitschriftenheftes oder des Kapitels:13
Seitenbereich:S. 4034
Datum1 Juli 2021
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Chemie IV - Physikalische Chemie (Solution Chemistry) > Prof. Dr. Werner Kunz
Identifikationsnummer
WertTyp
10.3390/molecules26134034DOI
Stichwörter / KeywordsOLIGOETHER CARBOXYLATES; WATER; ionic liquids; surface active ionic liquids (SAILs); room temperature ionic liquids (RTILs); alkyl ethylene glycol ether carboxylates; rare earth metals; transition metals; colloids; green chemistry
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-551991
Dokumenten-ID55199

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