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Rothe, Manuel ; Müller, Eva ; Denk, Patrick ; Kunz, Werner

Ionic Liquids Based on the Concept of Melting Point Lowering Due to Ethoxylation

Rothe, Manuel , Müller, Eva, Denk, Patrick and Kunz, Werner (2021) Ionic Liquids Based on the Concept of Melting Point Lowering Due to Ethoxylation. Molecules 26 (13), p. 4034.

Date of publication of this fulltext: 19 Dec 2023 06:37
Article
DOI to cite this document: 10.5283/epub.55199


Abstract

Most of the commonly used Ionic Liquids (ILs) contain bulky organic cations with suitable anions. With our COMPLET (Concept of Melting Point Lowering due to Ethoxylation), we follow a different approach. We use simple, low-toxic, cheap, and commercially available anions of the type C-x(EO)(y)CH2COO- to liquefy presumably any simple metal ion, independently of its charge. In the simplest case, the ...

Most of the commonly used Ionic Liquids (ILs) contain bulky organic cations with suitable anions. With our COMPLET (Concept of Melting Point Lowering due to Ethoxylation), we follow a different approach. We use simple, low-toxic, cheap, and commercially available anions of the type C-x(EO)(y)CH2COO- to liquefy presumably any simple metal ion, independently of its charge. In the simplest case, the cation can be sodium or lithium, but synthesis of Ionic Liquids is also possible with cations of higher valences such as transition or rare earth metals. Anions with longer alkyl chains are surface active and form surface active ionic liquids (SAILs), which combine properties of ionic and nonionic surfactants at room temperature. They show significant structuring even in their pure state, i.e., in the absence of water or any other added solvent. This approach offers new application domains that go far beyond the common real or hypothetical use of classical Ionic Liquids. Possible applications include the separation of rare earth metals, the use as interesting media for metal catalysis, or the synthesis of completely new materials (for example, in analogy to metal organic frameworks).



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleMolecules
Publisher:MDPI
Open Access Type:CC-License
Place of Publication:BASEL
Volume:26
Number of Issue or Book Chapter:13
Page Range:p. 4034
Date1 July 2021
InstitutionsChemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number
ValueType
10.3390/molecules26134034DOI
KeywordsOLIGOETHER CARBOXYLATES; WATER; ionic liquids; surface active ionic liquids (SAILs); room temperature ionic liquids (RTILs); alkyl ethylene glycol ether carboxylates; rare earth metals; transition metals; colloids; green chemistry
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-551991
Item ID55199

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