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NO product yield excitation spectrum of the S0 -> S2 transition of nitrosobenzene in a supersonic jet

Kessler, Angela, Kensy, Uwe and Dick, Bernhard (1998) NO product yield excitation spectrum of the S0 -> S2 transition of nitrosobenzene in a supersonic jet. Chemical Physics Letters 289 (5,6), pp. 516-520.

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Abstract

The absorption spectrum of the S0 -> S2 transition of ultracold PhNO in a supersonic jet was measured indirectly by monitoring the product yield of the NO fragment. The vibrational structure and relative line intensities agree well with the corresponding spectrum in an Ar matrix. The photofragmentation yield is const. for all vibronic S2-states up to an excess energy of 3500 cm-1. The electronic ...

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Item type:Article
Date:1998
Additional Information (public):CAN 129:108798 22-9 Physical Organic Chemistry 10102-43-9 (Nitric oxide) Role: FMU (Formation, unclassified), PRP (Properties), FORM (Formation, nonpreparative) (nitric oxide product-yield excitation spectrum of S0 -> S2 transition of nitrosobenzene in supersonic jet); 586-96-9 (Nitrosobenzene) Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (nitric oxide product-yield excitation spectrum of S0 -> S2 transition of nitrosobenzene in supersonic jet)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identification Number:
ValueType
1998:378840Other
Keywords:Fluorescence; Photolysis; Potential energy surface; UV and visible spectra; Vibronic transition (nitric oxide product-yield excitation spectrum of S0 -> S2 transition of nitrosobenzene in supersonic jet); Jets (supersonic, nitric oxide product-yield excitation spectrum of S0 -> S2 transition of nitrosobenzene in supersonic jet); nitrosobenzene photofragmentation fluorescence nitric oxide
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:5558
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