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LOV1 protein from Chlamydomonas reinhardtii is a template for the photoadduct formation of FMN and methylmercaptane

Lanzl, Karin ; Noell, Gilbert ; Dick, Bernhard


The adduct of FMN and methylmercaptane was synthesized inside the binding pocket of a light oxygen voltage sensitive (LOV) protein domain in which the cysteine residue of the wild type has been replaced by the photochem. inactive amino acid glycine. In the absence of the protein, the photoreaction between FMN and MM yields the fully reduced hydroquinone form FMNH2 or the anion FMNH. The reaction ...


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