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Metal-bis(oxazoline) complexes: From coordination chemistry to asymmetric catalysis

Rasappan, R. ; Laventine, D. ; Reiser, O.



Abstract

Metal-bis(oxazoline) complexes have proven to be one of the most versatile classes of chiral catalysts being able to promote a large variety of organic transformations. The coordination geometry and electronic properties play an integral role for the asymmetric induction exhibited by these complexes and, aided by X-ray structure analysis and NMR studies, rules have been recognized to understand ...

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