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Chiral Diselenophosphoric Acids for Ion Pair Catalysis: A Novel Approach to Enhance Both Proton Donating and Proton Accepting Properties

URN to cite this document:
urn:nbn:de:bvb:355-epub-582918
DOI to cite this document:
10.5283/epub.58291
Eder, Johannes ; Antonov, Alexander S. ; Tupikina, E. Y. ; Gschwind, Ruth M.
Date of publication of this fulltext: 22 May 2024 08:37

This publication is part of the DEAL contract with Wiley.


Abstract

The activation of poorly reactive substrates via strong chiral acids is a central topic in asymmetric ion pair catalysis these days. Despite highly successful scaffolds such as N-triflylphosphoramides, these catalysts either lack C2-symmetry or provide multiple H-bond acceptor sites, leading to lower ee values for certain reactions. We present BINOL-based diselenophosphoric acids (DSA) as an ...

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