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Cation-Binding of Glutamate in Aqueous Solution

URN to cite this document:
urn:nbn:de:bvb:355-epub-586251
DOI to cite this document:
10.5283/epub.58625
Friesen, Sergej ; Kruchinin, Sergey E. ; Fedotova, Marina V. ; Buchner, Richard
[img]License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 08 Jul 2024 12:41



Abstract

Interactions of the cations Li+, Na+, Mg2+, and Ca2+ with L-glutamate (Glu–) in aqueous solution were studied at room temperature with dielectric relaxation spectroscopy in the gigahertz region. Spectra of ∼0.4 M NaGlu with added LiCl, NaCl, MgCl2, or CaCl2 (c(MCln) ≤ 1.5 M) were evaluated and experiments supplemented by density functional theory and 3D reference interaction site model (3D-RISM) ...

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