Changing the Reactivity of Enediynes by Metal Ion Coordination (review)

URN to cite this document:: urn:nbn:de:bvb:355-epub-62046
DOI to cite this document:: 10.5283/epub.6204

König, B.

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Date of publication of this fulltext: 05 Aug 2009 13:51

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Abstract

The complex molecular structure and interesting activation mechanisms of naturally occurring enediynes have inspired the synthesis of a variety of simpler model systems to mimic their properties. While in most model compounds nucleophilic attack, isomerization or bioreduction are used to activate the unsaturated system for diradical cyclization, some attempts have been made to employ metal-ion ...