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Two-dimensional Arrays of Amphiphilic Zn2+ -cyclens for Guided Molecular Recognition at Interfaces

Turygin, D. S. ; Subat, M. ; Raitman, O. A. ; Selector, S. L. ; Arslanov, V. V. ; König, B. ; Kalinina, M. A.



Abstract

The sterically guided molecular recognition of nucleobases, phosphates, adenosine, and uridine nucleotides on Langmuir monolayers and Langmuir-Blodgett monolayers of amphiphilic mono- or bis(Zn2+-cyclen)s assembled on thiolated surfaces was investigated. The stepwise selective binding of metal ions, uracil, or phosphate by dicetyl cyclen monolayers with variously tuned structures at the air/water ...

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