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2´-Oxoethyl Flavin Revisited

Svoboda, J., König, B., Sadeghian, K. and Schütz, M. (2008) 2´-Oxoethyl Flavin Revisited. Z. Naturforsch. 63b, 47 - 54.

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The present work investigates the possibility of using 2'-oxoethyl flavin (2) as a starting material for the construction of more complicated flavin-based molecules. 2-Oxoethyl flavin (2), prepared by oxidative degradation of commercially available riboflavin 1, is however a rather untypical aldehyde. It prefers the hydrated gem-diol form 4 in aqueous solution. Ab initio electronic structure ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
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Keywords:Flavin, Aldehyde, Hydration, Nucleophilic Attack, Reductive Amination, Local MP2
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6282
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