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2´-Oxoethyl Flavin Revisited

Svoboda, J. ; König, B. ; Sadeghian, K. ; Schütz, M.



Abstract

The present work investigates the possibility of using 2'-oxoethyl flavin (2) as a starting material for the construction of more complicated flavin-based molecules. 2-Oxoethyl flavin (2), prepared by oxidative degradation of commercially available riboflavin 1, is however a rather untypical aldehyde. It prefers the hydrated gem-diol form 4 in aqueous solution. Ab initio electronic structure ...

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