Attenberger, B., Schmaderer, H. and König, B. (2008) Copper-mediated 3-N-Arylation of Flavin. Synthesis 11, 1767 - 1774.
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Abstract
A generally applicable method for the direct 3-N-arylation of flavins using arylboronic acids and copper acetate was developed. The reaction conditions were optimized considering the lability of flavins in basic conditions and thermal heating. Donor- and acceptor-substituted arylboronic acids were used yielding 3-N-arylflavins in moderate to good yields by C(aryl)-N(imide) bond formation. UV and ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2008 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | GRK 640 Sensory photoreceptors in natural and artificial systems | ||||
| Identification Number: |
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| Keywords: | flavin, N-arylation, boronic acid, isoalloxazin, microwave, copper catalysis | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 6290 |
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