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Copper-mediated 3-N-Arylation of Flavin

Attenberger, B., Schmaderer, H. and König, B. (2008) Copper-mediated 3-N-Arylation of Flavin. Synthesis 11, 1767 - 1774.

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A generally applicable method for the direct 3-N-arylation of flavins using arylboronic acids and copper acetate was developed. The reaction conditions were optimized considering the lability of flavins in basic conditions and thermal heating. Donor- and acceptor-substituted arylboronic acids were used yielding 3-N-arylflavins in moderate to good yields by C(aryl)-N(imide) bond formation. UV and ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
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Keywords:flavin, N-arylation, boronic acid, isoalloxazin, microwave, copper catalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6290
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