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Synthesis and structure of a heterocyclic ansa pyrrole amino acid

Dirscherl, G., Rooshenas, P., Schreiner, P.R., Lamaty, F. and König, B. (2008) Synthesis and structure of a heterocyclic ansa pyrrole amino acid. Tetrahedron 64, pp. 3006-3016.

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We report a synthetic route to ansa pyrrole amino acids via olefin ring-closing metathesis of diene precursors in the presence of Grubbs I catalyst. The dienes were prepared by Grignard addition to pyrrole sulfinyl imines. The success of the macrocyclic ring closure depends on the dienes structure and only in the case of the 13-membered compound 28 sufficient material could be isolated by ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6293
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