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Photooxidation of Benzyl Alcohols with Immobilized Flavins

Schmaderer, Harald, Hilgers, Petra, Lechner, Robert and König, Burkhard (2009) Photooxidation of Benzyl Alcohols with Immobilized Flavins. Advanced Synthesis & Catalysis 351, pp. 163-174.

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Benzyl alcohols are oxidized cleanly and efficiently to the corresponding aldehydes under irradiation using flavin photocatalysts and aerial oxygen as the terminal oxidant in homogeneous aqueous solution. Turnover frequencies (TOF) of more than 800 h⁻¹ and turnover numbers (TON) of up to 68 were obtained. Several flavin photocatalysts with fluorinated or hydrophobic aliphatic chains were ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
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Keywords:catalyst recycling; flavins; fluorous chemistry; immobilization; photooxidation; redox chemistry
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:7276
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