Schmaderer, Harald, Hilgers, Petra, Lechner, Robert and König, Burkhard (2009) Photooxidation of Benzyl Alcohols with Immobilized Flavins. Advanced Synthesis & Catalysis 351, pp. 163-174.
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Abstract
Benzyl alcohols are oxidized cleanly and efficiently to the corresponding aldehydes under irradiation using flavin photocatalysts and aerial oxygen as the terminal oxidant in homogeneous aqueous solution. Turnover frequencies (TOF) of more than 800 h⁻¹ and turnover numbers (TON) of up to 68 were obtained. Several flavin photocatalysts with fluorinated or hydrophobic aliphatic chains were ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2009 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | GRK 640 Sensory photoreceptors in natural and artificial systems | ||||
| Identification Number: |
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| Keywords: | catalyst recycling; flavins; fluorous chemistry; immobilization; photooxidation; redox chemistry | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 7276 |
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