Photocatalysis Enables Chemodivergent Radical Polar Crossover: Ritter‐Type Amidation vs Heck‐Type Olefin Carbofunctionalizations

URN to cite this document:: urn:nbn:de:bvb:355-epub-766601
DOI to cite this document:: 10.5283/epub.76660

Lepori, Mattia

; Pratley, Cassie

; Dey, Indrasish

; Butera, Valeria

; Roider, Veronika

; Barham, Joshua P.

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 08 May 2025 07:29

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Abstract

Three-component alkene difunctionalization reactions constitute an ideal platform to rapidly build molecular complexity, enabling the simultaneous introduction of two distinct, orthogonal functional groups into the C═C bond in a single step. Herein, a photoredox catalyzed Ritter-type carboamidation of electronically diverse styrenes harnessing non-stabilized, nucleophilic primary radicals ...